[AG Abs.15 P57] ORFEUS II Echelle Spectra: Interstellar Deuterium and Molecular Hydrogen towards BD +39 3226 The FUV echelle spectrum obtained during the ORFEUS II mission in Nov./Dec. 1996 is used to derive H I, D I, H_2, and metal column densities on the line of sight towards BD +39 3226. This sdO star is located at l=65.00, b=+28.77 in a distance of about 270 pc. It has a pure helium line spectrum in the optical and some additional lines of highly ionized metals in the UV, which are well separated from the interstellar lines because of the stellar radial velocity of v=-273 km/s. A theoretical fit to the Ly alpha line taking into account the stellar He II line ca. 1.57 A bluewards gives a H I column density of 1.12(+0.29/-0.23)x10^20 1/cm^2. This value is consistent with a curve-of-growth analysis of the D and H Lyman series, including Ly delta, epsilon, zeta, and kappa, which leads to N(H I)=1.6(+0.9/-0.6)x10^20 1/cm^2 and N(D I)=1.45(+0.50/-0.38)x10^15 1/cm^2. Averaging the N(H I) results we derive D/H=1.2(+0.5/-0.4)x10^(-5). We also investigated metal lines in ORFEUS and IUE spectra. Their column densities indicate only moderate depletion (<=1.7 dex), in agreement with the small E(B-V)=0.05 and the low abundance of H_2 (N(H_2)=4.8(+2.0/-1.6)x10^15 1/cm^2). H_2 is examined for absorption by rotational exitation states up to J=7. The column densities of these exitation states reveal a H_2 ortho-to-para ratio of 2.5, a Boltzmann excitation temperature of 130 K and UV-pumping with an equivalent temperature of <1800 K.